Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand

  • Bayan Faiq Department of Chemistry, Collage of Science, Salahaddin University-Erbil, Kurdistan Region, Iraq.
  • Bayan Omer Ahmad Department of Chemistry, Collage of Science, Salahaddin University-Erbil, Kurdistan Region, Iraq
Keywords: Acid hydrazone; complexes; synthesis.

Abstract

      Complexes with the general formula [M(LH)2]X2 where M=Mn(II),Co(II),Ni(II) and Cu(II)  LH= 4-acetylpyridine benzoyl hydrazone and X=chloride ion were synthesized. The structures were confirmed by IR spectroscopy, and characterized by elemental analyses, UV-vis, 1H.n.m.r 13C-n.m.r, and conductivity measurements. Molar conductance values in DMSO indicate that all complexes are electrolytes with mole ratio (1:2) and chloride ions not participate in coordination to central metal ion except Mn complex. The ligand act as bidentate, they  coordinates through azomethine nitrogen (>C=N-) and carbonyl oxygen׳s.

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Published
2021-10-20
How to Cite
Faiq, B. and Ahmad, B. (2021) “Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand”, Zanco Journal of Pure and Applied Sciences, 33(5), pp. 85-94. doi: 10.21271/ZJPAS.33.5.10.
Section
Biology and Medical Researches